Employees spend their time a lot in their organization than their homes, it is important that their relationship to their colleagues should be in a positive way as possible despite of their sexual identity to have a harmonious working environment. The objectives of this study are. 1) To identify the relationship between peer relationship and motivation among employees of XYZ BPO company.2) To determine the relationship between peer relationship and work performance. Based on the responses gathered from 150 LGBT employees, there is a significant relationship between peer relationship and work performance but it is quite low with the average of (r= .490). Meanwhile, Peer Relationship has a significant relationship to motivation with the average of (r=537).